Unoccupied states in Cu and Zn octaethyl-porphyrin and phthalocyanine

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Unoccupied states in Cu and Zn octaethyl-porphyrin and phthalocyanine.

Copper and zinc phthalocyanines and porphyrins are used in organic light emitting diodes and dye-sensitized solar cells. Using near edge x-ray absorption fine structure (NEXAFS) spectroscopy at the Cu 2p and Zn 2p edges, the unoccupied valence states at the Cu and Zn atoms are probed and decomposed into 3d and 4s contributions with the help of density functional calculations. A comparison with ...

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Zn(II)phthalocyanine molecules (ZnPc) were thermally deposited on a rutile TiO2(011) surface and on Zn(II)meso-tetraphenylporphyrin (ZnTPP) wetting layers at room temperature and after elevated temperature thermal processing. The molecular homo- and heterostructures were characterized by high-resolution scanning tunneling microscopy (STM) at room temperature and their geometrical arrangement an...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 2011

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.3592937